Electrolytic capacitor electrode comprising semiconductor core with film-forming metal coating

ABSTRACT

This invention relates to an electrode for an electrolytic capacitor comprising a compacted porous semiconductor body of valve metal coated particles.

United States Patent 1 1 Sterling et al. 451 J 2, 1973 [$4] ELECTROLYTIC CAPACITOR [56] References Cited ELECTRODE COMPRISING SEMICONDUCTOR CORE wrru FILM- UNITED STATES PATENTS FORMING MET (jgATING 2,299,228 10/1942 Gray et al ..317/230 3,256,468 6/1966 Jenny et a]. ..317/230 Inventors: ey ra k Ste g, War Eric 3,302,073 1/1967 Broodo ..317/230 Langley Bush, Matching Green, nr. 3,325,699 6/1967 Hellicar ..317/230 Harlow, both of England 3,430,108 2/1969 Daendliker et al. ..317/230 3,330,999 7/l967 Hellicar ..317/230 [73] Ass1gnee: International Standard Electric Cor- Poralion, New York Primary ExaminerJames D. Kallam [22] Filed; June 10 1971 Attorney-C. Cornell Remsen, Jr., Walter J. Baum, Paul W. Hemminger, Charles L. Johnson, Jr., Philip PP 151,903 M. Bolton, Isidore Togut, Edward Goldberg and Menotti J. Lombardi, Jr.

[52] U.S.Cl ..317/230 29/570 [51] 1111.0. .1161; 9/04 [57] ABSTRACT [58] Field of Search ..317/230, 231, 232, 233 This invention relates to an electrode for an electrolytic capacitor comprising a compacted porous semiconductor body of valve metal coated particles.

li'C n ms, l na sm ELECTROLYTIC CAPACITOR ELECTRODE COMPRISING SEMICONDUCTOR CORE WITII FILM-FORMING METAL COATING The invention relates to electrolytic capacitors, and

particularly to the valve-metal electrode thereof. In the manufacture of tantalum capacitor anodes from powdered tantalum it is known that a considerable part of the tantalum is used only as a contact and does not play an active part in the capacity forming mechanism. Since tantalum is a relatively rare and expensive metal it is reasonable to attempt to replace some, at least, of the contact tantalum in the body of the anode with a less expensive material. These arguments also apply to niobium and niobium/tantalum alloys used as capacitor anodes.

It has already been proposed to use tantalum (or other valv'e metal) coated ceramic, i.e., electrically insulating, particles for the material of the anode. However, this results in a significant series resistance in the anode due to the presence of a relatively large quantity of the insulating cores of the particles.

According to' the invention there is provided an electrode for an electrolytic capacitor comprising a compacted porous body of valve metal coated particles of electrically conducting material different from that of the coating.

The electrically conducting material of the particle core can be categorized under four types:

1. A metal or alloy, for example nickel or stainless steel, which is not a valve metal,

2. A metal or alloy, for example titanium for coating with tantalum, which is a different valve metal than that of the coating,

3. A non-metallic electrically conducting material, for example silicon carbide, and

4. An electrically conducting compound for example a lower oxide of titanium (TiO where x 2) which if exposed through the valve metal coating can subsequently be converted to a non-conducting form.

The provision of the valve metal coating 2 on particle cores 1, shown in the FIGURE, of any of the above categories is carried out by any suitable means, such as vapor deposition from a volatile compound of the valve metal performed by means of a fluidized bed technique, by plasma deposition or by sputtering.

For cores of category 4, electrically conducting TiO, may be coated in a fluidized bed of such particles at an elevated temperature of 1,000C using hydrogen. The combination of a reducing gas (hydrogen) and high temperature, results in the TiO being maintained in its conducting lower oxide form during deposition of the coating.

Having produced the valve metal coated particles,

the next'stage in the manufacture of a capacitor anode is the production of the porus'compac'ted anode body and the compaction techniques are to some extent determined by the particular category of the particle cores.

For category 1 and -3, e.g a nickel or silicon carbide core, the body is formed by subjecting the coated powder to isostatic compaction, in a similar manner to that described in our copending Application Ser. No. 16398/ (J. Lees C.H.L. Goodman C.S. Parfree 7- 4-1), which may be, butnot necessarily, followed by a heat treatment process to improve the electrical chwa teristics of the finis ed ca acitor.

it category 1 meta cor s, If the compaction and/or heat treatment process results in any significant to improve the electrical characteristics of the finished Y capacitor.

With category 2 cores, if the compaction and/or heat treatment process results in any exposure of the core metal through the coating, this exposed metal is also a valve metal and so the body is suitable for further processing in the capacitor manufacturing stage providing that a compatible electrolyte is used during anodization.

Finally for category 4 cores, the compaction may be solely by isostatic pressing on the one hand or solely by sintering at a high temperature on the other, e.g. 1600C for TiO, cores. These two method may be combined however and are not mutually exclusive.

As already indicated, if with category 4 cores there is exposure of core material through the valve metal coating, this exposed material can be converted to a nonconducting form. In the case of TiO cores, the subsequent anodizing, which is carried out in any conventional manner, results in any exposed TiO, being converted to TiO which is non-conducting and also plays an active role in the capacitor action.

The anodizing of the compacted porous bodies having valve metal coated particles with cores of categories l, 2 or 3 is also carried out in any conventional manner and the required further steps for the production of an electrolytic capacitor from these anode bodies, i.e., provision of electrolyte, cathode, lead attachement, housing and/or encapsulation are carried out in known manner.

It is to be understood that the foregoing description of specific examples of this invention is made by way of example only and is not to be considered as a limitation on its scope.

We claim 1. An electrode for an electrolytic capacitor comprising a compacted porous body of valve metal coated silicon particles.

2. An electrode for an electrolytic capacitor comprising a compacted porous body of valve metal coated silicon carbide particles.

3. An electrode according to claim- 1, wherein said valve metal is tantalum.

- t 1: 4 r. r 

2. An electrode for an electrolytic capacitor comprising a compacted porous body of valve metal coated silicon carbide particles.
 3. An electrode according to claim 1, wherein said valve metal is tantalum. 